论文部分内容阅读
在等离子体化学气相沉积系统(PECVD)中,使用高氢稀释硅烷(SiH_4)加乙烯(C_2H_4)为反应气氛制备了纳米硅碳(nc-SiC_x:H)薄膜。随着(C_2H_4+SiH_4)/H_2(X_g)从2%增加到5%时,由于H蚀刻效应的减弱,薄膜的晶态率从48%下降到8%,平均晶粒尺寸在3.5~10nm。当X_g≥6%时,生成薄膜为非晶硅碳(a-SiC_x:H)薄膜。nc-SiC~x:H薄膜的电学性质具有与薄膜的晶态率紧密相关的逾渗行为。本文将对nc-SiC_x:H薄膜的生长机制和晶化机制进行较详细讨论。
In the plasma chemical vapor deposition system (PECVD), a nanosilica-carbon (nc-SiC_x: H) thin film was prepared using high hydrogen diluted silane (SiH 4) plus ethylene (C 2 H 4) as the reaction atmosphere. With the increase of (C_2H_4 + SiH_4) / H_2 (X_g) from 2% to 5%, the crystallinity of the films decreased from 48% to 8% and the average grain size ranged from 3.5 to 10 nm due to the decrease of H etching effect. When X_g≥6%, the film is amorphous silicon carbon (a-SiC_x: H) film. The electrical properties of nc-SiC ~ x: H thin films are closely related to the crystalline rate of the films. In this paper, the growth mechanism and crystallization mechanism of nc-SiC_x: H thin films will be discussed in detail.