【摘 要】
：
The title complex, [Co_2(bpdc)_2(bim)_4]_n(bpdc=biphenyl-2,2′-dicarboxylate dianion, bim=benzimidazole), was synthesized in a aqueous solution and its crystal
【出 处】
：
Chemical Research in Chinese Universities
论文部分内容阅读
The title complex, [Co_2(bpdc)_2(bim)_4]_n(bpdc=biphenyl-2,2′-dicarboxylate dianion, bim=benzimidazole), was synthesized in a aqueous solution and its crystal structure was determined by means of X-ray diffraction. There are two different coordinated Co(Ⅱ) centers in the complex. The Co1 center has a deformed trigonal-bipyramidal geometry, while the Co2 center possesses a tetrahedral geometry. In addition, the two different coordination modes of bpdc ligands act as two kinds of bridges to link Co1 and Co2, resulting in a catena chain.
The title complex, [Co_2 (bpdc) _2 (bim) _4] _n (bpdc = biphenyl-2,2’-dicarboxylate dianion, bim = benzimidazole), was synthesized in a aqueous solution and its crystal structure was determined by means of X There are two different coordinated modes of bpdc ligands act (Co). There are two different coordinated modes of bpdc ligands act as two kinds of bridges to link Co1 and Co2, resulting in a catena chain.
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