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以 Keggin结构的钼磷酸 ( H3PMo1 2 O4 0 · 1 3 H2 O)与苯丙氨酸 ( Phe)为原料 ,利用一步固相化学反应于室温合成了纳米氨基酸杂多电荷转移配合物 ( HPhe) 3PMo1 2 O4 0 · 2 H2 O,采用元素分析 ,IR,XRD,TEM,UV和循环伏安法等手段对其进行了结构表征及性质研究 .结果表明 ,标题化合物纳米粒子为均匀的球状 ,粒径约为 3 0～ 40 nm.该化合物中杂多阴离子部分仍保持 Keggin结构 ,但在钼磷酸与苯丙氨酸之间发生了显著的电荷转移
In this paper, a series of heteropolyacid charge-transfer complexes (HPhe) 3PMo1 were synthesized by the one-step solid-phase reaction at room temperature using the phosphomolybdate (H3PMo1 2 O4 0 · 1 3 H 2 O) and phenylalanine (Phe) 2 O4 0 · 2 H 2 O, the structure and characterization were studied by elemental analysis, IR, XRD, TEM, UV and cyclic voltammetry.The results showed that the title compound nanoparticles were uniform spherical, particle size About 30 ~ 40 nm.The heteropolyanion in this compound still retains Keggin structure, but significant charge transfer occurs between molybdophosphate and phenylalanine