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Monosulfuron is a novel sulfonylurea herbicide with ultra-low dosage invented and patented by Nankai University. Herein its sodium salt was firstly synthesized and crystal structure was determined by X-ray diffraction method. The title compound belongs to the triclinic system, space group P1 with a = 7.306(6), b = 9.446(8), c = 11.872(10) , α = 76.578(14), β = 78.049(13), γ = 77.620(14)°, V = 767.7(11) 3, Mr = 377.32, Z = 2, Dc = 1.632 g/cm3, μ = 0.283 mm-1, F(000) = 388, R = 0.0444 and wR = 0.1186. In the title compound, Na(1) coordinates with O(4) and O(5) from one monosulfuron molecule, N(4A) and O(5A) from the other monosulfuron molecule and the oxygen atom from H2O to give five coordination bonds. The title complex is further linked into a three-dimensional structure through π…π interactions and intermolecular hydrogen bonds between the oxygen and nitrogen atoms.
Monosulfuron is a novel sulfonylurea herbicide with ultra-low dosage invented and patented by Nankai University. Herein its sodium salt was previously synthesized and crystal structure was determined by X-ray diffraction method. The title compound belongs to the triclinic system, space group P1 with α = 76.578 (14), β = 78.049 (13), γ = 77.620 (14) °, V = 767.7 (11) 3, Mr = 377.32, Z = 2, Dc = 1.632 g / cm3, μ = 0.283 mm-1, F (000) = 388, R = 0.0444 and wR = 0.1186. N (4A) and O (5A) from the other monosulfuron molecule and the oxygen atom from H2O to give five coordination bonds. The title complex is further linked into a three -dimensional structure through π ... π interactions and intermolecular hydrogen bonds between the oxygen and nitrogen atoms.