Enhancing Heterogeneous Catalytic Activity of Iron(II) Phthalocyanine by Ethanol and Its Application

来源 :Journal of Wuhan University of Technology(Materials Science | 被引量 : 0次 | 上传用户:ZHANQIWEI
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A chemical system for facile and accurate detection of 2,4-dichlorophenol(DCP) via iron(II) phthalocyanine(Fe(II)Pc) catalyzed chromogenic reaction is reported for the fi rst time. In this system, DCP could be oxidized by dioxygen with the catalysis of Fe(II)Pc and then coupled with 4-aminoantipyrine(4-AAP) to generate pink antipyrilquinoneimine dye. Control experiments showed that the addition of ethanol could obviously enhance the catalytic activity of heterogeneous Fe(II)Pc catalysts because of the partial dissolution of Fe(II)Pc nanocubes, which was confirmed by the SEM analysis. On the basis of the detection results of DCP in the range from 2×10-5 to 9×10-4 mol/L, we obtained a regression equation(A = 0.187 5 + 0.01 209C(R2=0.995 6)) with the detection limit(3σ) of 3.26×10-6 mol/L, which could be successfully used in detecting the real samples. A chemical system for facile and accurate detection of 2,4-dichlorophenol (DCP) via iron (II) phthalocyanine (Fe (II) Pc) catalyzed chromogenic reaction was reported for the fi rst time. In this system, DCP could be oxidized by dioxygen with the catalysis of Fe (II) Pc and then coupled with 4-aminoantipyrine (4-AAP) to generate pink antipyrilquinoneimine dye. Control experiments showed that the addition of ethanol could obviously enhance the catalytic activity of heterogeneous Fe (II) Pc catalysts because of the partial dissolution of Fe (II) Pc nanocubes, which was confirmed by SEM analysis. On the basis of the detection of DCP in the range from 2 × 10 -5 to 9 × 10 -4 mol / L, we obtained a regression equation (A = 0.187 5 + 0.01 209C (R2 = 0.995 6)) with the detection limit (3σ) of 3.26 × 10-6 mol / L, which could be successfully used in detecting the real samples.
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