超分子体系中的分子识别研究(ⅩⅦ)——几种有机硒修饰β-环糊精与脂肪醇的包结配位作用

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环糊精双核铜配合物以及磷酰基修饰环糊精可通过离子间的静电相互作用扩展对分子的键合能力和分子选择性[1~4].含有芳香基的修饰环糊精可通过主-客体间的几何互补和诱导楔合作用扩展手性对映体识别能力[5].本文用紫外-可见分光光度技术研究了几种有机硒修饰β... Cyclodextrin binuclear copper complexes and phosphoryl modified cyclodextrins can extend the bonding ability and molecular selectivity of the molecules through the electrostatic interaction between the ions [1 ~ 4]. Aromatics-containing modified cyclodextrins can extend the chiral enantiomeric recognition ability through the host-guest geometric complementation and the induced wedge-binding [5]. In this paper, UV-visible spectrophotometry of several organic selenium modified beta ...
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