Conformational effect on fluorescence emission of tetraphenylethylene-based metallacycles

来源 :中国化学快报:英文版 | 被引量 : 0次 | 上传用户:yangqimeng2008
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Herein,we designed and constructed two metallacycles,1 and 2,to illustrate the conformational effect of isomeric AIE fluoropho res on the platfo rm of supramolecular coordination complexe s(SCCs).Specifically,the dangling phenyl rings in TPE units of the
其他文献
精准时空信息如何赋能千行百业、大众生活?"5G+北斗"的产业化、大众化应用路在何方?在"十四五"和"新基建"的背景下,测绘地理信息产业如何另辟蹊径、奋楫扬帆……盛夏7月,带着对行业发展的思考,来自全国的20余名行业领导、业界专家、企业高管云集申城,共赴一场火热的思想盛会。
期刊
我是2007年2月8日入党的。回想自己的入党经历,可以用"三番两次"来形容,即写过三次入党申请书,履行过两次入党程序。1992年,我第一次向党组织递交了入党申请书。那年学校举办入党积极分子培训班,在取得结业证书后,很多同学都写了入党申请书。那时,我对党的认识还是懵懂的。但大家都写了,自己不写,岂不是显得落伍和不求上进呀?现在看来,那时写入党申请书有一定的从众心理,更像是表明一种态度,或者说是完成一
期刊
A pair of neolignan enantiomers with an unprecedented carbon skeleton,(+)-/(-)-angelignanine[(+)-/(-)-1],was isolated as minor components of an aqueous extract
Polypeptoids have been explored as mimics of polypeptides,owing to polypeptoidssuperior stability upon proteolysis.Polypeptoids can be synthesized from one-pot ring-opening polymerization of amino acid N-substituted N-carboxyanhydrides(NNCAs).However,th
A convenient synthetic protocol for the hexasubstituted benzene derivatives was successfully developed by DABCO promoted domino reaction of arylidene malononitrile with two molecules of dialkyl but-2-ynedioates.The domino reaction resulted in tetraalkyl 6
Rhodium(Ⅲ)-catalyzed[4+1]cyclization of azobenzenes with α-Cl ketones has been developed.3-Acyl-2H-indazoles could be easily afforded in up to 97%yields for more than 30 examples.The obtained products are potentially valuable in organic synthesis and drug
The stimulator of interferon genes(STING)shows promising clinical activity in infectious diseases and tumors.However,the lack of targeting capability and intracellular stability of STING agonists severely limits the therapeutic efficacy.Recently,drug deli
Pathological detection using immunohistochemistry(IHC)has become an indispensable process in the diagnosis confirmation of various cancers.However,the productio
In this paper,we demonstrate that modification of anion-transport active 1,3-bis(benzimidazol-2-yl)benzene with strongly electron-withdrawing trifluoromethyl an
An unprecedented tunable hydrophobic effect in self-assembly of a small cationic organic fluorophore(NI-TPy+)-based with aggregation-induced emission(AIE)proper