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A new 3-D porous Gd-Cu heterometallic polymer [Gd2Cu3(bpy)2(ip)6]·6H2O (1) (bpy = 2,2’-bipyridine, H2ip = isophthalic acid) has been hydrothermally synthesized and structurally characterized. Compound 1 crystallizes in the triclinic space group P1and displays a 3-D non-interpenetrated α-Po network with 1-D channels filled transversely by the hexa-nuclear chain-like (H2O)6. The EPR and thermal stability of 1 were investigated.
A New 3-D porous Gd-Cu heterometallic polymer [Gd2Cu3 (bpy) 2 (ip) 6] 6H2O (bpy = 2,2’-bipyridine, H2ip = isophthalic acid) has been hydrothermally synthesized and structurally characterized Compound 1 crystallizes in the triclinic space group P1 and displays a 3-D non-interpenetrated α-Po network with 1-D channels filled transversely by the hexa-nuclear chain-like (H2O) 6. The EPR and thermal stability of 1 were investigated .