Effects of Silylation on Zn-IM5 and Its Catalytic Activity for Butane Aromatization

来源 :China Petroleum Processing & Petrochemical Technology | 被引量 : 0次 | 上传用户:heephy
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Effects of silylation on surface properties and catalytic performance of Zn-IM5 for butane aromatization were studied in this paper. Collidine-IR and NH3-TPD analyses revealed that the silylation treatment not only decreased the quantity of both strong and weak acid sites but also led to a slightly reduced intensity of weak acidity. Silylation of the catalyst promoted the selectivity of BTX by narrowing the channel and cutting the acidity. The effect of temperature of silylation and amount of Si loading were evaluated. The best condition has specified a temperature of 50 ℃ and a SiO_2 loading of 4.0%. Effects of silylation on surface properties and catalytic performance of Zn-IM5 for butane aromatization were studied in this paper. Collidine-IR and NH3-TPD analyzes revealed that the silylation treatment not only decreased the quantity of both strong and weak acid sites but also led Silylation of the catalyst promoted the selectivity of BTX by narrowing the channel and cutting the acidity. The effect of temperature of silylation and amount of Si loading were evaluated. The best condition has specified a temperature of 50 ℃ and a SiO_2 loading of 4.0%.
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