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The title complex [(ArO)2(THF)Sm(μ-OH)]2·2THF (Ar = C6H2-tBu3-2,4,6) was obtained by the hydrolysis of divalent (ArO)2Sm(THF)3·THF in toluene. It crystallizes in monoclinic, space group P21/c with a = 14.7968(14), b = 18.6981(15), c = 16.8264(17