The inclusions of Al in steels have great influence on the properties and the quality of steels.But there are some difficulties on the content determination of Al inclusions with accuracy and rapidity.Conventional quantity analysis of stable inclusions is electrolysis method with the disadvantages of long analytical period,trivial operation and a little loss of some fine and instable oxides.The content of insoluble aluminum can be obtained by the subtraction between the content of total Al and acid soluble Al determined by chemical methods with the disadvantage of complicate procedure.Original position statistic distribution analysis(OPA) can be used for the determination of inclusions by collecting and discriminating the signals produced by single spark discharge in the way of no pre-sparking,scanning and emitting continuously.In this study the element of Al in some spectrum certified reference materials of carbon and medium or low-alloyed steels was analyzed by original opposition statistic distribution technique.Two quantitative mathematical models used by original position distribution analysis technology for the analysis of the content of Al inclusions have been investigated and been applied to the analysis of the content of Al inclusions in many kinds of spectrum certified reference materials and some medium and low-alloyed steel samples.The scope of application of the models and their limited conditions were discussed.It was found that the results calculated by OPA had great difference with the value by chemical method for some samples with the total content of Al above 0.2%.The reason is that some intensity of abnormal sparks have gone beyond the range of the largest intensity that can be determined by the instrument so that there is a certain deviation on the identification of abnormal sparks and the calculation of threshold value.It was found that the size distribution of Al inclusions had a great influence on the application of the two models.For most of certified reference materials for spectrum analysis and real steel samples the results of the content of Al in inclusions calculated by model 1 was satisfied and had good coincidence with the value of insoluble Al by chemical method. But for the samples with so many large inclusions of Al existed,the influence of intensity should be considered because the signal increase did not vary in the form of simple function.So model 2 was more suitable for the content calculation of Al in inclusions in this case.In order to choose suitable model to be used it is suggested that the size distribution of inclusions should be determined by OPA before content determination of Al in inclusions. The results of the content of Al inclusions calculated by the selected mathematical model were satisfied and had good coincidence with the value of insoluble Al obtained by the subtraction between the content of total Al and soluble Al determined by chemical methods when the content of total aluminum was below 0.2%. The inclusions of Al in steels have great influence on the properties and the quality of steels.But there are some difficult on the content determination of Al inclusions with accuracy and rapidity. Conventional quantity analysis of stable inclusions is electrolysis method with the defect of long analytical period, trivial operation and a little loss of some fine and instable oxides. The content of insoluble aluminum can be obtained by the subtraction between the content of total Al and acid soluble Al determined by chemical methods with the disadvantage of complicate procedure. distribution analysis (OPA) can be used for the determination of inclusions by collecting and discriminating the signals produced by single spark discharge in the way of no pre-sparking, scanning and emittingcontinuous. In this study the element of Al in some spectrum certified reference materials of carbon and medium or low-alloyed steels was analyzed by original opposition st atistic distribution technique. Two quantitative mathematical models used by original position distribution analysis technology for the analysis of the content of Al inclusions have been investigated and been applied to the analysis of the content of Al inclusions in many kinds of spectrum certified reference materials and some medium and low-alloyed steel samples. Scope of application of the models and their limited conditions were discussed. It was found that the results calculated by OPA had great difference with the value by chemical method for some samples with the total content of Al above 0.2 %. The reason is that certain intensity of abnormal sparks have gone beyond the range of the largest intensity that can be determined by the instrument so that there is certain certain deviation on the identification of abnormal sparks and the calculation of threshold value .It was found that the size distribution of Al inclusions had a great influence on the application of the two models.For most ofcertified reference materials for spectrum analysis and real steel samples the results of the content of Al in inclusions calculated by model 1 was satisfied and had good coincidence with the value of insoluble proteins by chemical method. But for the samples with so many large inclusions of Al existed, the influence of intensity should be considered because the signal increase did not vary in the form of simple function.So model 2 was more suitable for the content calculation of Al in inclusions in this case.In order to choose suitable model to be used it is suggested that the size distribution of inclusions should be determined by OPA before content determination of Al in inclusions. The results of the content of Al inclusions calculated by the selected mathematical model were satisfied and had good coincidence with the value of insoluble cc the subtraction between the content of total Al and soluble Al determined by chemical methods when the content of total aluminum was below 0.2%.