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The title complex has been synthesized and characterized by elementary analysis,FT-IR and Raman spectra. The crystal and molecular structure was determined by X-ray diffraction analysis. The crystal of this complex C6H18O12P3Eu(Mr = 527. 08) is monoclinic with space group P21/c and cell parameters a= 10. 418(2) ,b= 16. 596(6) ,c =10. 766(2) A ,β=111. 67(2)°,V=1729. 8(8) A3 and Z=4. Dimethyl phosphate an-ions coordinate with europium ions through double O-P-O bridges to form a special network of rings-linking-rings. The local coordination geometry of Eu is a slightly distorted octahedron.
The title complex has been synthesized and characterized by elementary analysis, FT-IR and Raman spectra. The crystal and molecular structure was determined by X-ray diffraction analysis. The crystal of this complex C6H18O12P3Eu (Mr = 527. 08) is monoclinic with space group P21 / c and cell parameters a = 10. 418 (2), b = 16. 596 (6), c = 10.766 (2) A, β = 111.67 (2) °, V = 1729.8 (8) A3 and Z = 4. Dimethyl phosphate an-ions coordinate with europium ions through double OPO bridges to form a special network of rings-linking-rings. The local coordination geometry of Eu is a slightly distorted octahedron.