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A new metal-organic complex Co2(cbba)4(phen)2(μ2-OH2)(H2cbba=2-(4’-chlorine-benzoyl)benzoic acid,phen=1,10-phenanthroline) 1 has been hydrothermally synthesized and struc-turally characterized by single-crystal X-ray diffraction,elemental analyses,TG and IR spectroscopy.The compound crystallizes in triclinic,space group P1 with a=10.7659(7),b=17.1856(11),c=19.2022(13),α=83.8120(10),β=84.9930(10),γ=87.2070(10)°,V=3515.8(4)3,C80H50Cl4Co2N4O13,Mr=1534.90,Dc=1.450 g/cm3,μ(MoKα)=0.693 mm-1,F(000)=1568,Z=2,the final R=0.0490 and wR=0.1092 for 8216 observed reflections(Ⅰ > 2σ(Ⅰ)).In the crystal structure,the cobalt atom is six-coordinated with three carboxylate oxygen atoms from three different cbba ligands,one oxygen atom from coordinated water molecule and two nitrogen atoms from phen ligand,showing a distorted octahedral geometry.Furthermore,it exhibits a 3D supramolecular network through π-π and hydrogen bonding interactions.
A new metal-organic complex Co2 (cbba) 4 (phen) 2 (μ2-OH2) (H2cbba = 2- (4’-chlorine- benzoyl) benzoic acid, phen = 1,10- phenanthroline) 1 has been hydrothermally synthesized struc-turally characterized by single-crystal X-ray diffraction, elemental analyzes, TG and IR spectroscopy. The compound crystallizes in triclinic space group P1 with a = 10.7659 (7), b = 17.1856 (11), c = ) α = 83.8120 (10) β = 84.9930 (10) γ = 87.2070 (10) ° V = 3515.8 (4) 3 C80H50Cl4Co2N4O13 Mr = 1534.90 Dc = 1.450 g / cm3 MoKα ) = 0.693 mm-1, F (000) = 1568, Z = 2, the final R = 0.0490 and wR = 0.1092 for 8216 observed reflections (I> 2σ -coordinated with three carboxylate oxygen atoms from three different cbba ligands, one oxygen atom from coordinated water molecule and two nitrogen atoms from phen ligand, showing a distorted octahedral geometry. Future Art, it exhibits a 3D supramolecular network through π-π and hydrogen bonding interactions .