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High-quality type-Ⅱa gem diamond crystals are successfully synthesized in a Ni70Mn25Co5-C system by temperature gradient method (TGM) at about 5.5 GPa and 1560 K. Al and Ti/Cu are used as nitrogen getters respectively.While nitrogen getter Al or Ti/Cu is added into the synthesis system, some inclusions and caves tend to be introduced into the crystals. When Al is added into the solvent alloy, we would hardly gain high-quality type-Ⅱa diamond crystals with nitrogen concentration Nc<1 ppm because of the reversible reaction of Al and N at high pressure and high temperature (HPHT). However, when Ti/Cu is added into the solvent alloy, high-quality type-Ⅱa diamond crystals with Nc<1 ppm can be grown by decreasing the growth rate of diamonds.