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合成了2个新的烯唑醇铜和银配合物:[CuL4Cl2](1),[AgL2]NO3(2)(L=diniconazole)。通过元素分析、红外光谱和X-ray单晶衍射对其结构进行了表征。结构分析表明,1属三斜晶系,P1空间群,晶胞参数为a=0.882 3(7)nm,b=1.370 5(10)nm,c=1.516 4(11)nm,α=91.507(11)°,β=97.356(9)°,γ=107.683(9)°。2属单斜晶系,P21/c空间群,晶胞参数为a=1.229 2(3)nm,b=1.272 1(3)nm,c=2.431 7(5)nm,β=98.694(3)°。1和2都由分子间氢键连接成一维链结构。
Two new eneconazole copper and silver complexes were synthesized: [CuL4Cl2] (1), [AgL2] NO3 (2) (L = diniconazole). Its structure was characterized by elemental analysis, IR and X-ray single crystal diffraction. The structural analysis shows that for a triclinic system, the space group P1 has a unit cell space of a = 0.882 3 (7) nm, b = 1.370 5 (10) nm, c = 1.516 4 11) °, β = 97.356 (9) °, γ = 107.683 (9) °. 2 belongs to the monoclinic space group P21 / c with cell parameters of a = 1.229 2 (3) nm, b = 1.272 1 (3) nm, c = 2.431 7 (5) nm and β = 98.694 (3) °. 1 and 2 are intermolecular hydrogen bonds into one-dimensional chain structure.