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A novel μ-S-bridged di-palladium(Ⅱ) complex, {[(phen)Pd( μ-SPr)2Pd(phen)](NO3)2·2H2O} (1) was synthesized and characterized by the 1H NMR, element analysis and single crystal X-ray diffraction. It crystallizes in the monoclinic space group C2/c with unit cell parameters: a=2.165 1(3) nm, b=1.291 4(2) nm, c=2.716 2(3) nm, β=111.987(3)°, and V=7.041 8(16) nm3, Z=8, R=0.054 4, wR=0.127 4. The X-ray crystal structure analysis revealed that two 1,10-phenanthroline palladium(Ⅱ) moieties were bridged by two n-propylmercapatan molecules in coplanar fashion with the dimensions of 1.55 nm × 0.88 nm. The plane-to-plane distance of the complex 1 is 0.33 nm, which reveals strong aromatic-aromatic π-π interaction. CCDC: 292998.
A novel μ-S-bridged di-palladium (Ⅱ) complex, {[(phen) Pd (μ-SPr) 2Pd (phen)] (NO3) 2 · 2H2O} It crystallizes in the monoclinic space group C2 / c with unit cell parameters: a = 2.165 1 (3) nm, b = 1.291 4 (2) nm, nm, β = 111.987 (3) °, and V = 7.041 8 (16) nm3, Z = 8, R = 0.054 4, wR = 0.127 4. The X-ray crystal structure analysis revealed that two 1,10-phenanthroline palladium (II) moieties were bridged by two n-propylmercapatan molecules in coplanar fashion with the dimensions of 1.55 nm × 0.88 nm. The plane-to-plane distance of the complex 1 is 0.33 nm, which reveals strong aromatic-aromatic π-π interaction CCDC: 292998.