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采用电化学方法制备了含不同粒度的CdS超微粒子薄膜电极,应用表面光电压谱和光电化学技术对电极的光电化学特性进行了研究。结果表明,这些电极具有明显的量子限域效应,同体相材料相比,CdS超微粒子薄膜电极显示出较高的光电响应,说明该薄膜电极具有独特的光电压和电荷传输机理。
Electrochemical methods were used to prepare CdS ultrafine particle electrode with different particle size. The photoelectrochemical properties of the electrode were investigated by surface photovoltage spectroscopy and photoelectrochemical techniques. The results show that these electrodes have obvious quantum confinement effect. Compared with bulk materials, CdS ultrafine particle electrode shows a high photoelectric response, indicating that the electrode has a unique photoelectric voltage and charge transport mechanism.