Trace Elements and Rare Earth Elements of Sulfide Minerals in the Tianqiao Pb-Zn Ore Deposit,Guizhou

来源 :Acta Geologica Sinica(English Edition) | 被引量 : 0次 | 上传用户:power_gq
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Trace elements and rare earth elements(REE) of the sulfide minerals were determined by inductively-coupled plasma mass spectrometry.The results indicate that V,Cu,Sn,Ga,Cd,In,and Se are concentrated in sphalerite,Sb,As,Ge,and Tl are concentrated in galena,and almost all trace elements in pyrite are low.The Ga and Cd contents in the light-yellow sphalerites are higher than that in the brown and the black sphalerites.The contents of Ge,Tl,In,and Se in brown sphalerites are higher than that in light-yellow sphalerites and black sphalerites.It shows that REE concentrations are higher in pyrite than in sphalerite,and galena.In sphalerites,the REE concentration decreases from light-yellow sphalerites,brown sphalerites,to black sphalerites.The ratios of Ga/In are more than 10, and Co/Ni are less than 1 in the studied sphalerites and pyrites,respectively,indicating that the genesis of the Tianqiao Pb-Zn ore deposit might belong to sedimentary-reformed genesis associated with hydrothermal genesis.The relationship between LnGa and LnIn in sphalerite,and between LnBi and LnSb in galena,indicates that the Tianqiao Pb-Zn ore deposit might belong to sedimentary-reformed genesis.Based on the chondrite-normalized REE patterns,δEu is a negative anomaly(0.13-0.88),andδCe does not show obvious anomaly(0.88-1.31);all the samples have low total REE concentrations(<3 ppm) and a wide range of light rare earth element/high rare earth element ratios(1.12-12.35).These results indicate that the ore-forming fluids occur under a reducing environment.Comparison REE compositions and parameters of sphalerites,galenas,pyrites,ores,altered dolostone rocks,strata carbonates,and the pyrite from Lower Carboniferous Datang Formation showed that the ore-forming fluids might come from polycomponent systems,that is,different chronostratigraphic units could make an important contribution to the ore-forming fluids.Combined with the tectonic setting and previous isotopic geochemistry evidence,we conclude that the ore-deposit genesis is hydrothermal,sedimentary reformed,with multisources characteristics of ore-forming fluids. Trace elements and rare earth elements (REE) of the sulfide minerals were determined by inductively-coupled plasma mass spectrometry. The results indicate that V, Cu, Sn, Ga, Cd, In, and Se are concentrated in sphalerite, Sb, Ge and Tl are concentrated in galena, and almost all trace elements in pyrite are low. Ga and Cd contents in the light-yellow sphalerites are higher than that in brown and the black sphalerites. The contents of Ge, Tl, In , and Se in brown sphalerites are higher than that in light-yellow sphalerites and black sphalerites. It shows that REE concentrations are higher in pyrite than in sphalerite, and galena.In sphalerites, the REE concentration decreases from light-yellow sphalerites, brown sphalerites , to black sphalerites. The ratios of Ga / In are more than 10, and Co / Ni are less than 1 in the studied sphalerites and pyrites, respectively, indicating that the genesis of the Tianqiao Pb-Zn ore deposit might belong to sedimentary- reformed genesis associated with hydrothermal genes is the relationship between LnGa and LnIn in sphalerite, and between LnBi and LnSb in galena, indicates that the Tianqiao Pb-Zn ore deposit might belong to sedimentary-reformed genesis. Based on the chondrite-normalized REE patterns, δEu is a negative anomaly (0.13-0.88), andδCe does not show obvious anomaly (0.88-1.31); all the samples have low total REE concentrations (<3 ppm) and a wide range of light rare earth element / high rare earth element ratios (1.12-12.35 ) These results indicate that the ore-forming inunes occur under a reducing environment. Comparison REE compositions and parameters of sphalerites, galenas, pyrites, ores, altered dolostone rocks, strata carbonates, and the pyrite from Lower Carboniferous Datang Formation showed that the ore -forming fluids might come from polycomponent systems, that is, different chronostratigraphic units could make an important contribution to the ore-forming fluids.Combined with the tectonic setting and previous isotopic geochemistry evidence, we conclude th atthe ore-deposit genesis is hydrothermal, sedimentary reformed, with multisource characteristics of ore-forming fluids.
其他文献
软件是计算机的灵魂,软件产业是全球范围内高科技产业中产值增长最为惊人的产业之一。在中国计算机产业整体水平相对较弱的情况下,与文化与国情紧密相关的软件产业被认为是
Biliary protein was isolated and purified by ammonium sulfate fraction ation and Sephadex G-75 gel filtration column chromatography. FTIR showed that w as a gly
阜宁实行干部待岗制周志军现实生活中,有那么一些为官者,说他没有成绩,他能振振有词地摆出几个花架子;说他有成绩,他没为老百姓办几件实事。群众需要解决的问题,他上推下卸,不闻不问
长期以来,由于受到传统教育思想的影响,广大师生在教学中曾出现了重书本、轻实践、重理论、轻实验、重知识、轻素质的现象。学生的智力受到压抑,能力得不到正常发展。当今的
因材施教是目前素质教育环节最提倡的教育方式之一,“分层次教学”正是在此背景下对高中数学教学环节进行的创新实践。通过利用分层次教学对自己教学实践进行改进,高中数学课
1986年,青海省围绕经济体制改革这个中 心任务,紧紧抓住经济承包责任制中的安全管 理,大力宣传贯彻最高人民检察院和劳动人事 部联合颁发的《关于查处重大责任事故的几项 暂
要钱不要命的经营思想害死人!建湖县的重大事故又是一例。 建湖县颜单乡建筑公司的领导为了多赚几个钱,竞然在修建168米高的工程时不设上下通道和安全网,要—人爬井架、乘吊
如今,消费者到市场买肉,最担心的不是缺斤短两的问题,而是害怕买上没经过检疫的病死猪肉,其后果难以预料。一位30岁的男青年,两年前患猪囊虫病,发病后经常抽风,两年以后虽然治愈,但智力
每年都要开总结会,每次也都要和过去有个比较。那么应该比些什么呢?一些领导开口就比企业过去的经济效益,讲今天的成绩如何;比过去的工资收入,讲今天的水平提高。伊然一派领导有方
期刊
国务院在7月 4日发出的《关于加强工业企业管理若干问题的决定》中,对企业提出了“抓管理、上等级、全面提高素质” 的严格要求,并就劳动保护、安全生产工作作了明确的规定。