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我们已合成、表征了两系列烷基钴席夫碱类型的辅酶B_(12)模型化合物;并对它们在溶液中Co—C键的稳定性进行了研究。这两个系列分别是RCo(salen)L及一类新型辅酶B_(12)模型RCo(SB)L,其中R为甲、乙、
We have synthesized and characterized two series of alkyl cobalt Schiff base coenzyme B 12 model compounds, and studied the stability of their Co-C bond in solution. The two series are RCo (salen) L and a new class of coenzyme B_ (12) model RCo (SB) L, where R is A, B,