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在基态,由弱的电荷转移所形成的缔合体,一般称之为“电荷转移络合体”,这种络合体的液相光化学反应,早已引起有机化学家的极大兴趣,并已进行了广泛的研究;近年来,对电荷转移络合体的固相光化学反应也越来越引起化学家的注意,但二茂铁(Fc)和四氰基乙烯(TCNE)的电荷转移络合体(Fc-TCNE)在固相或液相的光化学反应都未见报道,我们对其固相和液相光化学反应进行了研究,得到了不同的产物,
In the ground state, the association formed by weak charge transfer, commonly referred to as “charge-transfer complex,” has long been of great interest to organic chemists and has been carried out by liquid-phase photochemical reactions of such complexes In recent years, solid-state photochemical reactions of charge-transfer complexes have drawn more and more attention from chemists. However, charge transfer complexes of ferrocene (Fc) and tetracyanoethylene (TCNE) (Fc-TCNE) in the solid or liquid photochemical reactions have not been reported, we have its solid phase and liquid phase photochemical reactions were studied, different products were obtained,