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用光度法测定了四苯骈卟啉（Ｈ２ＴＢＰ）与ＣＵ２＋、Ｚｎ２＋配位反应速率常数、活化能及热力学参数．结果表明：Ｈ２ＴＢＰ与Ｃｕ２＋配位反应速率较快，△Ｈ＜０，而与Ｚｎ２＋配位速率较慢，且△Ｈ＞０．报导了ＺｎＴＢＰ的荧光光谱，ＣｕＴＢＰ的ＥＳＲ谱．
The coordination rate constant, activation energy and thermodynamic parameters of tetraphenylporphyrin (H2TBP) with CU2 + and Zn2 + were determined by spectrophotometry. The results show that the coordination reaction between H2TBP and Cu2 + is faster, △ H <0 and slower than Zn2 +, and △ H> 0. The fluorescence spectra of ZnTBP and the ESR spectra of CuTBP were reported.