A New Chain-like Copper(Ⅱ) Polymer:[Cu(MOPIP)(BDC)]_n·0.5n(H_2O)

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A metal-organic coordination compound formulated as [Cu(MOPIP)(BDC)]n·0.5n(H2O) 1 (MOPIP=2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10] phenanthroline=BDC=1,4-benze Nedicar- boxylate) has been hydrothermally synthesized and structurally characterized by elemental analysis=thermogravimetric analysis=IR spectrum=and single-crystal X-ray diffraction. The title compound crystallizes in the triclinic system=space group P1=with a= 8.872(5)=b=11.163(6)=c=12.589(6)=α=94.687(7)=β=99.930(6)=γ=103.074(7)°=V=1186.7(12)3=C28H19CuN4O5.5=Mr=563.01=Dc=1.576 g/cm3=μ(MoKα)=0.973 mm-1=F(000)=576=Z=2=the final R=0.0607 and wR=0.1618 for 3419 observed reflections (I>2σ(I)). A metal-organic coordination compound formulated as [Cu (MOPIP) (BDC)] n · 0.5n (H2O) 1 (MOPIP = 2- (4-methoxyphenyl) -1H-imidazo [4,5-f] ] phenanthroline = BDC = 1,4-benze Nedicar-boxylate) has been hydrothermally synthesized synthetically characterized by elemental analysis = thermogravimetric analysis = IR spectrum = and single-crystal X-ray diffraction. The title compound crystallizes in the triclinic system = space group P1 = with a = 8.872 5 = b = 11.163 6 = c = 12.589  = α = 94.687 = β = 99.930 6 = γ = 103.074 ° = V = 1186.7  3 = C28H19CuN4O5.5 = Mr = 563.01 = Dc = 1.576 g / cm3 = μ (MoKα) = 0.973 mm -1 = F (000) = 576 = Z = 2 = the final R = 0.0607 and wR = 0.1618 for 3419 observed reflections (I> 2σ (I)).
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