Experimental and computational assessment of 1,4-Dioxane degradation in a photo-Fenton reactive cera

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The present study evaluated a photo-Fenton reactive membrane that achieved enhanced 1,4-Dioxane removal performance.As a common organic solvent and stabilizer,1,4-Dioxane is widely used in a variety of industrial products and poses negative environmental and health impacts.The membrane was prepared by covalently coating photocatalyst of goethite (α-FeOOH) on a ceramic porous membrane as we reported previously.The effects of UV irradiation,H2O2 and catalyst on the removal efficiency of 1,4-Dioxane in batch reactors were first evaluated for optimized reaction conditions,followed by a systematical investigation of 1,4-Dioxane removal in the photo-Fenton membrane filtration mode.Under optimized conditions,the 1,4-Dioxane removal 2)rate reached up to 16% with combination of 2 mmol/L H2O2 and UV365 irradiation (2000 μW/cm2) when the feed water was filtered by the photo-Fenton reactive membrane at a hydraulic retention time of 6 min.The removal efficiency and apparent quantum yield (AQY) were both enhanced in the filtration compared to the batch mode of the same photo-Fenton reaction.Moreover,the proposed degradation pathways were analyzed by density functional theory (DFT) calculations,which provided a new insight into the degradation mechanisms of 1,4-Dioxane in photo-Fenton reactions on the functionalized ceramic membrane.
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