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The title mononuclear zinc(II) complex [Zn(BCDP)(H2O)2] (BCDP = N,N’-bis(3,5- dichlorosalicylidene)-1,3-diaminopropane) was prepared and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The crystal belongs to the orthorhombic system, space group Pnma with a = 7.887(1), b = 23.788(2), c = 10.295(4) , Z = 4, V = 1931.5(8) 3, Dc = 1.786 g/cm3, Mr = 519.49, λ(MoKα) = 0.71073 , μ = 1.853 mm-1, F(000) = 1048, R = 0.0464 and wR = 0.0918. A total of 2273 unique reflections were collected, of which 1570 with I > 2σ(I) were observed. The molecule of the complex has crystallographic mirror symmetry. The Zn atom is six- coordinated in an octahedral geometry. In the crystal, the molecules are linked through intermo- lecular O-H…O and O-H…Cl hydrogen bonds, forming chains running along the a axis.
The title mononuclear zinc (II) complex [Zn (BCDP) (H2O) 2] (BCDP = N, N’- bis (3,5-dichlorosalicylidene) -1,3-diaminopropane was prepared and characterized by elemental analysis, IR The crystal belongs to the orthorhombic system, space group Pnma with a = 7.887 (1), b = 23.788 (2), c = 10.295 4, Z = 4, V = 1931.5 (8) 3, Dc = 1.786 g / cm3, Mr = 519.49, λ (MoKα) = 0.71073 , μ = 1.853 mm -1, F (000) = 1048, R = 0.0464 and wR = of 2273 unique reflections were collected, of which 1570 with I> 2σ (I) were observed. The molecule of the complex has crystallographic mirror symmetry. The Zn atom is six-coordinated in an octahedral geometry. In the crystal, the molecules are linked through intermo- lecular OH ... O and OH ... Cl hydrogen bonds, forming chains running along the a axis.