无光条件下天然叶绿素的催化加氢反应

来源 :中国科学技术大学学报 | 被引量 : 0次 | 上传用户:xiaodehuwei12
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
It is found that the natural chlorophyll can carry out hydrogenation reaction by the Ni cluster catalyst at normal temperature (10℃±2℃) and normal pressure in the dark. Along with the reaction going on, the fresh green color of chlorophyll fades gradually and become colorless in the end. Methods of Ultra violet spectrum, High effect liquid chromatogram, Gas chromatogram on line and X ray diffraction are employed to detect the reactants and the products. After reaction, the original chlorophyll A and chlorophyll B disappear; while some small molecules are found, such as CH 4, NH 3, KMgH 3. The reagents chlorophyll and hematoporphyrin are used as standerd references. The TEM image shows the catalyst particle size is within 3 nm~5 nm in the diameter. It is clear that after catalytic hydrogenation, both the porphyrin cycle and the pyrrole structure are broken. Perhaps the reaction imitates the natural decomposition of chlorophyll under reducing conditions (for example, under the deep sea) in nature. In the deep sea there are high pressure, small organic molecules, and very hot fluid with nm metal coming out of the bottom. From the view point of thermodynamics, it is possible to carry out a reverse reaction of the one mentioned above; and seen in this respective, life could have come from the sea. In fact, the porphyrin cycle is stable in natural environment in the Et OH solution of chlorophyll remained for one year, and in the Et OH solution of dead leaves. It can be found intact in both and it can still carry out similar catalytic reactions. Further experiments are conducted by using pyrrole and tetra hydrogen pyrrole as the reactants to carry out catalytic hydrogenation, and the results show that at normal temperature and pressure the pyrrole cycles are also broken and small molecule gases such as CH 4, C 3H 6, C 4H 10 , C 4H 8 are formed. It is found that the natural chlorophyll can carry out hydrogenation reaction by the Ni cluster catalyst at normal temperature (10 ° C ± 2 ° C) and normal pressure in the dark. Along with the reaction going on, the fresh green color of chlorophyll fades gradually and become colorless in the end. Methods of Ultra violet spectrum, High effect liquid chromatogram, Gas chromatogram on line and X ray diffraction are employed to detect the reactants and the products. After reaction, the original chlorophyll A and chlorophyll B disappear; while some small molecules are found, such as CH 4, NH 3, KMgH 3. The reagents chlorophyll and hematoporphyrin are used as standerd references. The TEM image shows the catalyst particle size is within 3 nm ~ 5 nm in the diameter. It is clear that after catalytic hydrogenation, both the porphyrin cycle and the pyrrole structure are broken. Perhaps the reaction imitates the natural decomposition of chlorophyll under reducing conditions (for example, unde In the deep sea there are high pressure, small organic molecules, and very hot fluid with nm metal coming out of the bottom. From the view point of thermodynamics, it is possible to carry out a reverse reaction of the one mentioned above; and seen in this respective, life could have come from the sea. In fact, the porphyrin cycle is stable in natural environment in the EtOH solution of chlorophyll remained for one year, and in the EtOH solution of Further experiments are conducted by using pyrrole and tetra hydrogen pyrrole as the reactants to carry out catalytic hydrogenation, and the results show that at normal temperature and pressure the pyrrole cycles are also broken and small molecule gases such as CH 4, C 3 H 6, C 4 H 10, C 4 H 8 are formed.
其他文献
英语教材中课文是教学的依据,除了具有语言功能以外,还承载着话题和写作结构等多方面的功能信息。作为英语教师要充分地利用和合理整合教材的写作资源,为学生的写作活动提供
离合器是连接发动机和变速箱的重要部件,驾驶员可根据驾驶需求,踩踏或松开离合器踏板,使发动机与变速箱缓慢结合或分离,能够实现平稳起车或停车.
“芙蓉城内仁济院,旧时名称四圣祠。巴山蜀水天府国,悬壶济世锦江边。百年沧桑百年情,仁心救世仁心济。”说的是环境优美、景色怡人的成都市第二人民医院。医院学科体系完善,专业
近几十年,胃癌的发病率有所下降,但仍然是全球癌症相关死亡的主要恶性肿瘤之一[1‐2]。肿瘤特异性的细胞信号通路异常或分子遗传学改变与肿瘤患者的预后及对治疗的反应密切相关,是
摘要:近年来,伴随信息媒介技术的发展,大量关于狗患的新闻被报道出来。广大民众与养狗人之间的关系,因为狗患的存在而变得难以和谐。狗患已经到了污染公共环境、威胁人类身心安全、冲击社会管理秩序的程度,治理狗患刻不容缓。  关键词:刑事;治理;狗患  中图分类号:D924 文献标识码:A 文章编号:2095-4379-(2016)29-0131-01  作者简介:刘信涛(1979-),男,汉族,河北衡水人
吴中诗派为明代文坛重镇.明中叶李梦阳崛起文坛,倡导复古,其目的是要重振传统悠久的古典主义文风,其真正批评的对象是宋元以来文学的世俗化趋势,而吴中作家正是这种趋势的重
[摘 要]高职院校教师聘任制施行以来,对促进高职院校的改革发展起到了积极的作用,但在实施的过程中也发现了许多问题,本文就高职院校中教师聘任制发挥的作用,及当前存在的问题进行了分析,并提出了一些合理化的对策和建议,以期对高职院校教师聘任制改革发展有所帮助。  [关键词]高职院校 教师 聘任制 研究    教师聘任制作为一种新型用人制度,其本质是淡化身份管理,实行岗位管理,是实现高职院校教师的管理体制
目的 分析手术室全期护理在手术室优质护理中的应用效果.方法 选取2018年10月~2019年5月在本院接受手术治疗的患者160例为研究对象,根据患者接受治疗的时间先后顺序将其分为对
摘要:电子通信技术在社会生活中的作用越来越显著,计算机技术改变传统的信息获取,而且人们之间的信息沟通往来也变得电子数据化,在当前的社会纠纷案件中,电子证据越来越多,在司法实践中电子物证在揭示案件真相有着重要的作用。对于电子物证,我国的《证据法》中认定的电子证据主要是视听资料,但是对于电子物证的关联性认定上依然存在不足,电子物证具有脆弱性以及容易被伪造的特点,因此对于电子物证的真伪难以认定的情况下,
4月28日,江泽民同志在中国人民大学考察工作时强调:我们要始终高度重视哲学社会科学在治党治国和建设有中国特色社会主义事业中的巨大作用,高度重视哲学社会科学领域高等教育