合成了Cu、Co两个系列卟啉金属配合物 17个 ,其中 8个新化合物未见文献报道 ,通过元素分析、IR、UV、1HNMR、MS对合成的化合物进行了表征 ,确证了其结构 .总结了Cu、Co与卟啉类配体配合的IR、UV、1HNMR判据 .研究了这两个系列化合物的液晶性能 ,发现 7个化合物具有液晶性质 Seven Cu and Co series porphyrin metal complexes were synthesized. Eight novel compounds were not reported in the literature. Their structures were confirmed by elemental analysis, IR, UV, 1HNMR and MS. The IR, UV and 1H NMR criteria for the coordination of Cu and Co with porphyrin ligands were summarized.The liquid crystal properties of these two compounds were investigated and seven compounds were found to have liquid crystal properties