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The crystal and molecular structures of (μ-PhCH2S)(μ-CH3C(O)CH2S)-Fe2(CO)6 have been determined by X-ray diffraction technique. The complex has chemical formula of C16H12O7S2Fe2 and Mr=492.08. The crystals are tri-clinic, space group P1,with a=8.461(5), b=10.937(5), c=ll.419(4)A,α=81.61 (3), β=78.21(4),γ=71.04(4)°,V=974.5A3, Dc=1.68 gcm-3,μ(MoKα)=17.3cm-1, Z=2,F(000)=495.93. The final R was 0.038 for 2874 independent reflections.
The crystal and molecular structures of (μ-PhCH2S) (μ-CH3C (O) CH2S) -Fe2 (CO) 6 have been determined by X-ray diffraction technique. The complex has chemical formula of C16H12O7S2Fe2 and Mr = space group P1 with a = 8.461 (5), b = 10.937 (5), c = ll.419 (4) A, α = 81.61 (3), β = 78.21 (4), γ = 71.04 (4) °, V = 974.5A3, Dc = 1.68 gcm-3, μ (MoKα) = 17.3 cm -1, Z = 2, F (000) = 495.93. The final R was 0.038 for 2874 independent reflections.