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A novel compound 5-o-[1-(3-ethoxymethyl-4-phenyl-5-ethoxycarbonyl-6-methyl-3,4-dihydropyrimidin-2-one)butoxy]phenyl-10,15,20-triphenyl zinc porphyrin(C_(65)H_(56)N_6O_5Zn) was synthesized and characterized by NMR,FT-IR and MS. The compound crystallizes out from chloroform and methanol mixture solution,and its crystal structure was measured by single-crystal X-ray diffraction,monoclinic system,space group P2_1/c with a = 17.2741(6),b = 16.3797(6),c = 41.0919(16) ?,b = 93.810(3)°,V = 11601.0(7) ?~3,Z = 4,S = 1.021,F(000) = 5000,R = 0.0749 and wR = 0.1771. Additionally,it has been revealed by X-ray analysis that Zn of porphyrin is coordinated with carbonyl O of dihydropyrimidinone,thus the porphyrin and pyrimidinone rings are distorted by the Zn–O coordination bond.
A novel compound 5-o- [1- (3-ethoxymethyl-4-phenyl-5-ethoxycarbonyl-6-methyl-3,4-dihydropyrimidin-2-one) butoxy] phenyl-10,15,20-triphenyl zinc porphyrin (C_ (65) H_ (56) N_6O_5Zn) was synthesized and characterized by NMR, FT-IR and MS. The compound crystallizes out from chloroform and methanol mixture solution, and its crystal structure was measured by single-crystal X-ray diffraction monoclinic system, space group P2_1 / c with a = 17.2741 (6), b = 16.3797 (6), c = 41.0919 (16) ?, b = 93.810 (3) °, V = 11601.0 = 4, S = 1.021, F (000) = 5000, R = 0.0749 and wR = 0.1771. Additionally, it has been revealed by X-ray analysis that Zn of porphyrin is coordinated with carbonyl O of dihydropyrimidinone, thus the porphyrin and pyrimidinone rings are distorted by the Zn-O coordination bond.