自1977年以来,苏联乌克兰科学院物理化学研究所(设于敖德萨)几乎集中了全所的科研力量致力于冠醚的研究工作。现根据乌克兰科学院院士的报告,对该所工作作一简要介绍。该物理化学研究所的科学家合成了下列结构的冠醚(1～9),其中化合物7～9对Ca~(2+)的选择性特别好(图1,表1)。他们还合成了对Na~+有选择性的冠醚(这类配体非常少)。 Since 1977, the Institute of Physical Chemistry of the Soviet Union Ukrainian Academy of Sciences (located in Odessa) has focused almost exclusively on the research efforts of the Institute. According to the report of the academician of the Academy of Sciences of Ukraine, I will make a brief introduction of the work of the institute. The physicists at the Institute of Physical Chemistry synthesized crown ethers (1 to 9) of the following structures, of which compounds 7 to 9 were particularly selective for Ca 2+ (Fig. 1, Table 1). They also synthesized crown ethers selective for Na ~ + (very few of these ligands).