桥联聚倍半硅氧烷作为一种新型的有机 无机杂化材料在近十年的研究中引起了人们的极大关注 ,这种材料的单体可以通过不同的合成方法获得 ,为材料的设计和剪裁提供了极大的便利。本文综述了桥联聚倍半硅氧烷单体的合成方法 ,对其在光学、催化、吸附等方面的应用作了评述 ,同时将发光稀土配合物引入桥联聚倍半硅氧烷的研究作了介绍 ,最后对桥联聚倍半硅氧烷将来的发展趋势作了展望 Bridged polysilsesquioxane as a new type of organic-inorganic hybrid materials in the past decade has caused great concern in the study, the monomer of this material can be obtained by different synthetic methods for the material Design and tailoring provide great convenience. This review summarizes the synthesis of bridged polysilsesquioxane monomers and reviews the applications in optical, catalysis, adsorption and so on. At the same time, the introduction of luminescent rare earth complexes into bridged polysilsesquioxanes Made a presentation, and finally made a prospect of the future development trend of bridged polysilsesquioxane