【摘 要】
：
Two salicylate containing mononuclear manganese complexes formulated as [Mnand characterized by elemental analysis, IR and single-crystal X-ray diffraction anal
【机 构】
：
State Key Laboratory of Structural Chemistry,Graduate School of the Chinese Academy of Sciences
【基金项目】
：
the Science & Technology Innovation Foundation for the Young Scholar of Fujian Province;国家自然科学基金
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Two salicylate containing mononuclear manganese complexes formulated as [Mnand characterized by elemental analysis, IR and single-crystal X-ray diffraction analyses. Crystal data for compound 1: monoclinic, space group C2/c, a=30.748(6), b=8.1933(13), c=21.137(4) (A), β=126.772(4)°, V=4265.5(13)(A)3, Z=8, Mr=471.34, Dc=1.468 g/cm3, μ=0.667 mm-1, F(000)=1952,the final R=0.0637, wR=0.1783 (I ＞ 2σ(I)) and GOOF=1.073; and those for compound 2: monoclinic,space group C2/c, a=14.505(5), b=11.048(4), c=20.711 (7)(A), β=103.603(6)°, V=3225.6 (18)(A)3, Z=4, Mr=668.65, Dc=1.377 g/cm3, μ=0.466 mm-1, F(000)=1416, the final R=0.0373, wR=0.1125 (I ＞2σ(I)), and GOOF=1.000. The Mn atoms of both complexes are six-coordinated in an axially elongated octahedral geometry for 1 and an axially compressed octahedral geometry for 2, and their oxidation states have been determined to be trivalent by bond valence sum calculation.
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