CO_6相关论文
气体软氮化渗层包括表面化合物层和扩散层。表面疏松是表面化合物层的主要缺陷。它严重影响着软氮化表面硬度、接触疲劳强度、抗......
簇合物Co_4(μ_3-S)〔P(S)(OCH_3)_2〕_2(CO)_9、Co_4(μ,η~2-S_2)〔P(O-i-C_3H_7)_2〕_2(CO)_(10)和Co_6(μ_3-S)_2(μ-“非
由 Co2 (CO) 8与 3个含硫、磷杂原子的有机前配体反应 ,得到两个四核和一个六核含硫、磷原子配位分子片的新颖钴羰基簇合衍生物 .......
DESULPHURIZATION THROUGH THE CLEAVAGE OF C-S BOND-PREPARATION AND STRUCTURAL CHARACTERIZA-TION OF TH
The crystal of cluster [Co6(μ3-S)8(PPh3)6] 2DMF CH3OH(1)was obtained by the reaction of CoCl(PPh3)3 with Na2pdt(H2pdt=......
(R_3P)_(4-n)CoX_n(R=Ph,Et等;X=Cl,Br;n=1,2)与Na_2E_x(E=S,Se;x=1,2)在DMF或DMF/乙醇介质中反应得到了一系列六核钴的原子簇化合......
Quasi－aromaticity in Cluster Chemistry Ⅲ． Localized Molecular Orbital Study on Electron－rich Cobalt－
Ｑｕａｓｉ－ａｒｏｍａｔｉｃｉｔｙｉｎＣｌｕｓｔｅｒＣｈｅｍｉｓｔｒｙＩＩＩ．ＬｏｃａｌｉｚｅｄＭｏｌｅｃｕｌａｒＯｒｂｉｔａｌＳｔｕｄｙｏｎＥｌｅｃｔｒｏｎ－ｒｉｃｈＣｏｂａｌｔ－ｓｕｌｆｕｒＣｌｕｓｔｅｒＣｏｍｐｏｕｎｄｓ［Ｃｏ_６（μ_３－Ｘ）_...
Quasi-aromaticity inCluster Chemistry III. Localized Molecular OrbitalStudyonElectron-richCobalt-sulfurCluster......
The electronic structures of clusters Co6(μ3-E)8(CO)6(E:-S,-Se) have beencalculated by using the DV-SCC-Xα method. The......
Quasi－aromaticity in Cluster Chemistry Ⅱ． Localized Molecular Orbital Studies on 〔Co_6（CO）_（14）〕~（4－
Ｑｕａｓｉ－ａｒｏｍａｔｉｃｉｔｙｉｎＣｌｕｓｔｅｒＣｈｅｍｉｓｔｒｙⅡ．ＬｏｃａｌｉｚｅｄＭｏｌｅｃｕｌａｒＯｒｂｉｔａｌＳｔｕｄｉｅｓｏｎ〔Ｃｏ_６（ＣＯ）_（１４）〕~（４－）ａｎｄ〔Ｎｉ_２Ｃｏ_４（ＣＯ）_（１４）〕~（２－）ＣｌｕｓｔｅｒＡｎｉ?..
Quasi-aromaticity inCluster Chemistry II. Localized Molecular Orbital Systems [Co_6 (CO) _ (14)] ~......
用Ｃｏ２（ＣＯ）８与含硫含磷杂环配体ＣｌＰＳＣＨ２ＣＨ２ＣＨ２Ｓ↓反应，合成得到含有半填隙μ６－Ｐ原子的新的六核簇Ｃｏ６（μ６－Ｐ）（μ－ＳＣＨ２ＣＨ２ＣＨ２Ｓ）（μ－ＰＳＣＨ２ＣＨ２ＣＨ２Ｓ↓）（ＣＯ）１２１，同时，得到三核簇Ｃｏ３（μ－ＰＳＣＨ２ＣＨ２ＣＨ２Ｓ↓）３（ＣＯ）６２，通过元素分析和波谱表征确定了二个......
