Ruthenium(Ⅱ)相关论文
Synthesis and Catalytic Application in Transfer Hydrogenation of 2,6-Bis(imidazo[1,2-a]pyridin-2-yl)
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合成了咪唑并[f]邻菲咯啉(IP)和2-苯基咪唑并[f]邻菲咯啉(PIP)两种新的配体及[Ru·(bp)2(IP)] ̄(2+)(简称b2IP)、[Ru(bpy)2(PIP)] ̄(2+)(简称b2PIP)、[Ru(phen)2(IP)] ̄(2+)(简称p2IP)和[Ru(phen)2(PIP)] ̄(2+)(简称p2PIP)4种新混配物。用电子吸收、稳态发光、圆二......
以(bpy)2Ru(AFO)^t2+,(phen)2Ru(AFO)^2+(AFO)^2+(bpy=2,2’-联吡啶;phen=1,10-邻菲罗啉;AFO=4,5-二氮杂萄酮)为先驱体,与苯肼,2,4-二硝基苯肼反应分别制得4种新的钌(Ⅱ)多吡啶配合物,用元素分析,红外光谱,紫外可见光谱,荧光......