During recent years,with the emergence of a large number of studies on transition-metal-catalyzed C-H bond activation,C-H bond functionalization has also become an appealing and convenient tool to con
Transition-metal-catalyzed decarboxylative coupling reactions was one of the highlights for the formation of carbon-carbon bond,which have shown great potential in synthetic organic chemistry.
The development of Ca-mediated reactions is of great importance and demand in modern organic chemistry.[1] In this work,we found that calcium iodide could efficiently promote the transformation of var
Ferrocene-based phosphine ligands are of fundamental importance in transition metal-catalyzed organic reactions.[1] Achiral ferrocene phosphine such as 1,1-bis(diphenylphosphino) ferrocene(DPPF),[2] h
The generation of α-imino gold carbenes through gold-catalyzed alkyne amination has received considerable attention in recent years,as this chemistry would offer the great potential to build structura
2,3-Allenols are highly desired building blocks in advanced organic synthesis.The transition metal catalyzed ring openings(SN2′-type) of propargyl epoxides with organometallic reagents such as Grignar
Poly(lactide acid)(PLA) has gained considerable attention because of their renewable,biodegradable and biocompatible characteristic over the past several decades.