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芳香性是芳香化学的基石,传统上,芳香性研究主要集中于π芳香体系,而σ芳香体系的研究很少.2015年,我们报道了首例不饱和体系中σ芳香性占主导的芳香化合物——锇杂戊搭烯并环丙烯2 [1](Figure-1A),该化合物是八个原子的碳链与金属的螯合物,我们称之为八碳龙配合物.
碳龙化学:不饱和碳链一锅法构筑金属杂戊搭烯并环丙烯
【摘 要】
：
芳香性是芳香化学的基石,传统上,芳香性研究主要集中于π芳香体系,而σ芳香体系的研究很少.2015年,我们报道了首例不饱和体系中σ芳香性占主导的芳香化合物——锇杂戊搭烯并环丙烯2 [1](Figure-1A),该化合物是八个原子的碳链与金属的螯合物,我们称之为八碳龙配合物.
【机 构】
：
厦门大学化学系,361005
【出 处】
：
第十九届全国金属有机化学学术讨论会
【发表日期】
：
2016年7期
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