【摘 要】
：
A synthesis of 2-epi-fagomine via a highly stereoselective gold(Ⅰ)-catalyzed allene cyclization is described.The stereochemical outcome of the cyclisation is opposite to that observed in previous stud
【机 构】
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Division of Chemistry and Biological Chemistry,School of Physical and Mathematical Sciences,Nanyang
【出 处】
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The 24th International Society of Heterocyclic Chemistry Con
论文部分内容阅读
A synthesis of 2-epi-fagomine via a highly stereoselective gold(Ⅰ)-catalyzed allene cyclization is described.The stereochemical outcome of the cyclisation is opposite to that observed in previous studies.In contrast, gold(Ⅲ)-catalysed cyclization is inefficient and gives rise to double cyclization by-products.
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