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Liquid lithium was regarded as the candidate materials of the coolant.The liquid lithium of the strong corrosive may be corrosion the structural materials.In this study in order to provide some reference for the compatibility of liquid lithium and the structural materials(316 L stainless steel).The SEM,EDX and the home-made LIBS tools were used to investigate the corrosion behaviors of 316L stainless steel in liquid lithium at 350℃ for 500h.