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5. 膦-亚磷酰胺酯配体催化α-羰基膦酸酯的不对称催化氢化

膦-亚磷酰胺酯配体催化α-羰基膦酸酯的不对称催化氢化

来源 :中国化学会全国第十二届有机合成化学学术研讨会 | 被引量 : 0次 | 上传用户：beakerzhou

【摘 要】

：

Optically active α-hydroxy phosphonates[1] are an important class of compounds because of their biological and medical activities.Although asymmetric hydrogenation of β-keto phosphonates,α-and β-keto

【作 者】

：

侯传金 胡向平 

【机 构】

：

大连工业大学轻工与化学工程学院 大连 116034;中国科学院大连化学物理研究所 大连 116023

【出 处】

：

中国化学会全国第十二届有机合成化学学术研讨会

【发表日期】

：

2015年7期

【关键词】

：

Asymmetric hydrogenation chiral phosphine-phosphoramidite ligand α-keto phosphat 

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　　Optically active α-hydroxy phosphonates[1] are an important class of compounds because of their biological and medical activities.Although asymmetric hydrogenation of β-keto phosphonates,α-and β-keto esters has achieved great success,the asymmetric hydrogenation of α-keto phosphonates surprisingly remains scare explored.

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