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  5. 若干5,10,15,20-四(4-羧基苯基)卟啉金属配合物的合成及热稳定性研究

若干5,10,15,20-四(4-羧基苯基)卟啉金属配合物的合成及热稳定性研究

来源 :中国化学会第十六届全国化学热力学和热分析学术会议 | 被引量 : 0次 | 上传用户：ZGGILOVE
【摘 要】
：
5,10,15,20-tetra(carboxyphenyl)porphyrin and its complexes were synthesized and characterized by the element analysis,conductivity,UV-Vis,IR,NMR,ESI-MS.Thermogravimetry(TG) and differential scanning c
【作 者】
：
曾锦萍 黄浩 刘万云 梅光泉 应惠芳 
【机 构】
：
宜春学院 江西省高校应用化学与化学生物学重点实验室,江西宜春 336000;宜春学院化学与生物工程学院,江西宜春 336000
【出 处】
：
中国化学会第十六届全国化学热力学和热分析学术会议
【发表日期】
：
2012年9期
【关键词】
：
meso-tetra(4-carboxyphenyl)porphyrin complexes synthesis thermal analysis 
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论文部分内容阅读
　　5,10,15,20-tetra(carboxyphenyl)porphyrin and its complexes were synthesized and characterized by the element analysis,conductivity,UV-Vis,IR,NMR,ESI-MS.Thermogravimetry(TG) and differential scanning calorimetry(DSC) for all compounds in an atmosphere of N2 were performed.The results showed the complexes have higher thermal stability than ligand.The Ni-TCPP complex has the highest thermal stability,and thermal stability of other complexes can be ranked as Ru-TCPP ≈ Pt-TCPP > Pd-TCPP > VO-TCPP > Zn-TCPP > Cu-TCPP from high to low.
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