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本文是通过合成三价钴的某些八面体配合物并测定其电子光谱,同时根据光谱数据分别计算Co~(3+)离子在各配体场中的分裂能△_0值,将△_0值由小而大的顺序排列,即得到Co（Ⅲ）某些配合物的光谱化学序。
In this paper, some octahedral complexes of trivalent cobalt were synthesized and their electronic spectra were determined. At the same time, the splitting energy △ _0 of Co ~ (3+) ions in each ligand field were calculated respectively according to the spectral data, From small to large order, that is, get the spectral chemical order of some complexes of Co (Ⅲ).