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Reduced graphene oxide nanosheets(rGONs)and p-type Cu2O nanoparticles(CNPs)were deposited onto n-type TiO2 nanotube arrays(TNAs)electrode by using cycle voltammetry(CV)method in order to fabricate a novel CNPs/rGONs/TNAs p-n heterojunction photoelectrode.The synthesized photoelectrode was characterized by FE-SEM,TEM,XRD,UV-visible diffuse reflectance spectra and its photoelectrochemical properties were investigated through linear sweep voltarnmetry(LSV),transient photocurrent,electrochemical impedance spectra(EIS)and Mott-Schotcky(M-S)test.The enhanced visible light absorption was observed in CNPs/rGONs/TNAs p-n heterojunction photoelectrode.The largely improved separation of photo-induced electron and hole was revealed by photocurrent measurement.