A series of isostructural 3D lanthanide metal-organic frameworks(Ln-MOFs),[Ln(tftpa)1.5(2,2-bpy)(H2O)](Ln = Gd 1,Eu 2 and Tb 3,H2tftpa = tetrafluoroterephthalic acid)have been synthesized by hydrother
Metal–metal-bonded compounds with low-valent metal centers have attracted much attention because they often exhibit specific reactivity towards small molecules and can afford novel adducts/complexes t
Transition-metal imido species are implicated as key intermediates in important transition-metal catalyzed transformations,e.g.C-H amination,olefin aziridation,dinitrogen functionalization,and have th
The precisely controlled polymerization of diene and styrene by using rare-earth metal catalysts will be reported.The pincer-type ligands stabilized rare-earth metal complexes catalyse the polymerizat