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  5. Four pillar-layer 3d-4f heterometallic coordination polymers based on isonicotinate acid and 1,4-nap

Four pillar-layer 3d-4f heterometallic coordination polymers based on isonicotinate acid and 1,4-nap

来源 :第九届全国无机化学学术会议 | 被引量 : 0次 | 上传用户：hehe521_
【摘 要】
：
Four novel three dimensional(3D)3d-4f heterometallic coordination polymers,namely,[Ln12Cu31I27(ina)34(NDC)3(H2O)12]n.2nH2O [Ln = Sm(1),Eu(2),Gd(3),Tb(4); NDC = 1,4-naphthalenedicarboxylate,Hina = ison
【作 者】
：
Chao Wu Junling Song Jinfang Zhang Chi Zhang 
【机 构】
：
China-Australia Joint Research Center for Functional Molecular Materials,School of Chemical and Mate
【出 处】
：
第九届全国无机化学学术会议
【发表日期】
：
2015年7期
【关键词】
：
Heterometallic coordination polymer Pillar-layer Syntheses 
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　　Four novel three dimensional(3D)3d-4f heterometallic coordination polymers,namely,[Ln12Cu31I27(ina)34(NDC)3(H2O)12]n.2nH2O [Ln = Sm(1),Eu(2),Gd(3),Tb(4); NDC = 1,4-naphthalenedicarboxylate,Hina = isonicotinic acid],have been hydrothermally synthesized and characterized by elemental analysis,FT-IR spectra,thermogravimetric analysis(TGA)and X-ray single-crystal diffraction.
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