配位超分子体系具有优异的光、电、磁性能和自组装特性,因此在配位化学、生物催化、分子器件以及材料科学等领域都有着重要的理论和研究意义.1很多文献表明,多氮杂环阳离子是优良的有机模版,将其和过渡金属进行自组装,可以得到了一系列超分子化合物.鉴于此,我们先合成了三齿阳离子L：1,3,5-三-(亚甲基三乙基胺)苯三溴盐.2然后让其与碘化银自组装成超分子化合物.单晶衍射表明,化合物1通过氢键形成具有三维结构
多酸(全称多金属氧酸盐,POMs)化学的发展至今已有近两百年的历程,是无机化学领域的一个重要分支。由于多酸优异的酸性、氧化还原性、结构可调谐性和热稳定性,使其被广泛应用各个领域,包括催化、材料、制药等领域[1]。
Development of Cu-based complex electrocatalysts is more easily to achieve a high activity and selectivity for reducing CO2 to multi-carbon hydrocarbons,exploring the synergistic effect between Cu and
Engineering the morphology of nanomaterials and modifying their electronic structure are effective ways to improve their performance in electrocatalysis.
Multifunctional nanocomposites for image-guided cancer therapy are highly desired in clinical application.Herein,a novel theranostic agent based on gold and ferroferric oxide nanoparticles coating pol