Phosphorus-containing compoundsplay important roles in many areasincludingorganometallic catalysis,organocatalysis,agro-and materials chemistry.1 For example,they have served as versatile ligands in t
One imidazole macrocyclic divalent cation did2+with flexible configuration was chosen with the aim of the immobilization of its conformation.1 One novel organic-inorganic hybrid supramolecule {[syn/an
In this article,five compounds {[BHMTA] [Cu2(SCN)3]}n(1),{[BHMTA] [Cu2I3]}n(2),{[BHMTA]2[CdI4]}(3)and {[BHMTA]2[Pb2I6]}n(4)were successfully synthesized via the self-assembly ofmetal salts and N-benzy
配位超分子体系具有优异的光、电、磁性能和自组装特性,因此在配位化学、生物催化、分子器件以及材料科学等领域都有着重要的理论和研究意义.1很多文献表明,多氮杂环阳离子是优良的有机模版,将其和过渡金属进行自组装,可以得到了一系列超分子化合物.鉴于此,我们先合成了三齿阳离子L:1,3,5-三-(亚甲基三乙基胺)苯三溴盐.2然后让其与碘化银自组装成超分子化合物.单晶衍射表明,化合物1通过氢键形成具有三维结构
多酸(全称多金属氧酸盐,POMs)化学的发展至今已有近两百年的历程,是无机化学领域的一个重要分支。由于多酸优异的酸性、氧化还原性、结构可调谐性和热稳定性,使其被广泛应用各个领域,包括催化、材料、制药等领域[1]。