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Photoelectrochemical properties of dyes have attracted considerable attention due to their proving important fundamental data for practical applications of dyes in photoelectric conversion devices.Here, a photoelectric conversion electrostatically self-assembled film consisting of a copolymer containing both weakly and strongly charged pendant groups, poly(4-styrenesulfonic acid-co-maleic acid) (PSSMA) and a bichromophore hemicyanine of (E)-1,1-(propane-1,3-diyl)b is(4-(4-(dimethylamino)styryl) pyridinium) bromide (H3) was prepared by electrostatic self-assembly technique.