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Three complexes of compositions TiL2(NMe2)2(1),TiL2(NEt2)2(2)and TiL2(OiPr)2(3)(HL = 3-(1H-pyrrol-2-yl)imidazo[1,5-a]pyridine)has been synthesized.All complexes have been characterized by elemental analyses and NMR studies.