During the past few years,the fabrication of thin polymer films with regular array of micropores(honeycomb films)has promoted the development of novel techniques in chemistry,biology,and material science.In this study,we utilized breath figure method to fabricate honeycomb films.On the basis of resultant honeycomb film with regular spherical pores,we further constructed two novel structures with the desired optical feature of either full angle independence or composite angle responses.Though filling colloidal crystals inside the pores,we fabricated colloidal crystal beads,which have spherical symmetry.