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A benzoxazine monomer (VB-a) containing an allyl groups was synthesized through the Mannich condensation of bisphenol A, formaldehyde, and allylamine.This monomer was then blended with unmodified, acid modified, and amine modified multiwalled carbon nanotubes (MWCNTs) separately, followed by thermal curing to form MWCNT/poly(VB-a) nanocomposites.