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The ground state reaction,Al(2P1/2)+O2(X3)→ AlO(X2Σ+)+O(3PJ),was studied at collisional energy 2.4 kcal/mol in our crossed molecular beam and time sliced ion imaging apparatus.The rovibrational states of AlO products were detected via(1+1)resonance-enhanced multiphoton ionization through the intermediate state D2Σ+.